The per-item thresholds work the same as before. You place the station control combinator and send item signals to it, those will become the new thresholds for those items.
You could use this combinator to send those signals since it works like a regular constant combinator. But there's not much point since sending virtual and Cybersyn signals to the second station combinator doesn't do anything.
So my recommendation would be to use the Cybersyn constant combinator for your main station combinator, and then a regular constant combinator connected to the station control combinator for the threshold overrides.
Hopefully that makes it clear, otherwise let me know!