That doesn't sound right... it's also something controlled by the game engine, not the mod.
10% means that there's a 10% chance that when the recipe completes, you'll get one of these items. It's also a CHANCE, which means, getting one is like rolling a 10 sided dice, and only getting one if you get a 10 showing, which means it is possible you've just been really unlucky and haven't scored a 10 yet.
Also... don't just look at the statistics... I've been made aware of an issue where, because some of my materials are listed as Catalysts, they might not show up on the productions screen. Actually check the machine to see if it made any Plutonium.