Basically, the only ones you're supposed to be able to vent are stage 1 gasses, such as hydrogen, oxygen, nitrogen and chlorine, which are all made in pairs... the list was extended mostly to byproducts, like sulfur dioxide, and the list keeps getting bigger as people request it.
Ammonia was never added as a venting option because it was always something you had to make on purpose, but now I guess it's also a byproduct in the chain leading up to making RTGs.
Personally, I have this chain balanced, so the output feeds back to the input, then you don't need to put ammonia in there anymore, but the moment you start using productivity modules, that would break... so I guess I'll consider adding it to the vent list.