TBH I have no idea what a 'Junction symbolic link' is... On Linux I just use:
ln -s /path/to/huge/external/storage/TLBE ~/.factorio/script-output/tlbe-mygame-1
and it works. (make sure to first move the existing 'tlbe-mygame-1' folder to the external location!)
AFAIK this creates a (regular) symbolic link, as said no idea about the Junction ones.