Hey there. So this mod has 2 settings - and suspending attacks during the day is off by default, and this is done to minimize interference with other AI mods such as rampant or rocket silo construction. I would recommend using this default mode if you have other biter AI mods such as those.
If you do enable the feature, what will happen is the newly spawned biters will (assuming Nightfall finds them) be put into "pause" mode until night. It... would be kind of tricky to do case by case exceptions. So I think if you do want attacks during daytime, just leave Nightfall on default settings.
This way, you'll get normal biter attacks, attacks from rocket silo construction and other mods, and then Nightfall will also send some biters at you during the night and shouldn't interfere with any other mods. The experimental mode is really just for those that want attacks only at night, yes ...and by necessity that can, by its nature, interfere with other mods.