Boilers don't always connect to turbines. I looked at raw.txt and a serpent.log after your changes, and I see that the boiler has a -1.5 for y as the fluid output before and -.5 after, even though it should be resized 1/2. I'll hack something in for my local version but you can figure out the right thing to do.
Related, warptorio2's factory planet gives me a pretty self-descriptive error:
26.274 Error ModManager.cpp:1332: Error while loading entity prototype "wsf-big-refinery" (assembling-machine): Invalid pipe connections specification for offset {-1.5000000000, -2.0000000000}. The offset must be outside of the entity bounding-box
I saw the note of the chem plant, if the pipe connections are fixed in these cases it might fix the chem plant.
Edit: Changed fluid box rounding to nearest 1/4 instead of nearest 1/2. Looks to work for boilers.