I'm going to document the default hotkeys in the Information portion when I release a new version.
Regarding the labels, they should start appearing pretty much immediately one-by-one. The whole process takes time depending on your map size. The mod normally prints out any errors that occur, but something unusual must have happened. You can try switching to the "old algorithm" in the Mod Settings.
As I've said in a different thread, I don't have much motivation in further updating this mod, I would probably advise you to switch to something that's actively maintained, like https://mods.factorio.com/mod/resourceMarker (which you may have already done, given it's been 8 months, sorry...)
Nonetheless, if you send me your save file, I can look into it and see if I find out an error. Thank you!