I noticed a few items that have recursive/nonsensical spoilage and I wasn't sure if they were intentional or not:
- Spoilage <-> Yumako Mash
- U-238/U-235 <-> U-235/U-238 / U-238/U-235
- Barrel <-> Water Barrel (Kinda funny way to get water, actually)
- Asteroid Chunk <-> Itself
The first three don't make sense, but they don't really cause any major problems either.
The asteroid chunks spoiling into themselves is pretty annoying when on a planet (other than Vulcanus) though, since the only way to get rid of them is to destroy their container, or send them up to space to crush/toss.
I also noticed items with multiple recipes only spoil into the ingredients of one (e.g. Rocket Fuel only spoils into Jelly recipe items), but that might just be a deliberate choice I suppose.