Accumulators don't work in power plant buildings, since the energy acceptor is an accumulator too and accumulators don't share energy. It is intentional that the energy acceptor is an accumulator, because otherwise the machines inside a power plant building would not receive priority power.
Accumulators inside power plants will only be used as backup power for the machines inside, in case power production stops for any reason. If you want to use accumulators for energy buffers, you need to place them outside your power plants.